CHỈ DẪN AN TOÀN DẦU TẨM CÁP DENIC

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertaking
Product identifier:
   Product name: ROPE HC-17
   Product code (SDS NO): 670221-1
Relevant identified uses of the substance or mixture and uses advised against
   Relevant identified uses of the product: Lubricating, Anti-rust Oil for Wire rope
Details of the supplier of the safety data sheet
   Manufacturer/Supplier: HOKOKU OIL CO.,LTD.
   Address: 2-6 Takasago Takaishi-City Osaka-Prefecture
   Division: Division of Product Development
   Telephone number: +81-72-268-1584
   FAX: +81-72-269-2115
 

2. Hazards identification
Classification of the substance or mixture
Specific Physical and Chemical hazards
   Even if there is no description in the above precautionary statement according to the GHS classification, give sufficient consideration to safety measures / first aid / storage / disposal with reference to the following information.
 

3. Composition/information on ingredients
Mixture/Substance selection:
   Mixture
Chemical identification: Lubricating oil(Lubricating base oils and Additives)

4. First-aid measures
Descriptions of first-aid measures
   General measures
      Get medical advice/attention if you feel unwell.
IF INHALED
Call a POISON CENTER/doctor/physician if you feel unwell.
IF ON SKIN (or hair）
Take off immediately all contaminated clothing. Rinse skin with water or shower.
IF IN EYES
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED
Seek medical advice immediately and show this container or label.

Most important symptoms/effects
   No useful information at present.
Protective measures for first aid
   Protect yourself by wearing rubber gloves and air-tight safety goggles.

5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media
In case of fire, use foam, dry powder, CO2 to extinguish.
Unsuitable extinguishing media
Do not use direct water jet.
Specific hazards arising from the substance or mixture
Will form toxic carbon oxides, sulfur oxides upon combustion.
Advice for firefighters
Specific fire-fighting measures
Evacuate non-essential personnel to safe area.
Shut off fuel to fire if possible to do so without hazard.
Apply water from a safe distance to cool and protect surrounding area.
On the occasion of fire extinguishing work, execute from the windward, if possible.
Special protective equipment and precautions for fire-fighters
Wear protective gloves/protective clothing/eye protection/face protection.
 

6. Accidental release measures
Personnel precautions, protective equipment and emergency procedures
Evacuate area.
Keep unauthorized personnel away.
Wear proper protective equipment.
PUBLIC SAFTY: Ventilate closed spaces before entering.
Environmental precautions
Prevent spills from entering sewers, watercourses or low areas.
Do not wash away into sewers or waterway.
In case of release on the sea, use of chemical agent, must suit to a technical standard
decided by ordinance of the Ministry of Transport.
Methods and materials for containment and cleaning up
For large spill, dike for later disposal.
Sweep up, place in a bag and hold for waste disposal.
In case of small spill, absorb the residues into sand or sawdust.
Absorb or cover with dry earth, sand or other non-combustible material and transfer to
containers.
In case of release on the sea, prevent from diffusion expanding an oil fence, and absorb
that using such as oil absorbing mat.
Preventive measures for secondary accident
Prepare extinguishers before catching fire.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
When a leak happened, report to the related organs immediately to prevent accident and
avoid expansion.
 

7. Handling and storage
Precautions for safe handling
Preventive measures
(Exposure Control for handling personnel)
Use pump to take out of container. Do not suck out by mouth with using tube.
(Protective measures against fire and explosion)
Ground and bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Take action to prevent static discharges.
Do not put pressure on empty container. It may explode.
Do not weld, heat, drill or cut the container. Residual material may catch fire with explosion.
Avoid contact with flame, spark or high temperature object, and do not release vapor recklessly.
(Exhaust/ventilator)
Exhaust/ventilator should be available.
(Safety treatments)
Avoid contact with skin.
Avoid contact with eyes.
When repair or process the equipment that left hazardous material, conducting after remove
it completely at a safe place.
Safety Measures
Wash hands et al thoroughly after handling.
Handle with normal temperature, and be careful with contamination of water or alien substance.
Any incompatibilities
Be careful not to come into contact with halogens, strong acids, alkalis, or oxidizing substances.
Storage
Conditions for safe storage
Keep container tightly closed.
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
(Incompatible storage condition)
Avoid storage in the same place as halogens, strong acids, alkalis and oxidizing substances.
Avoid heat, spark, fire and accumulation of static electricity.
(Incompatibilities)
Be careful with contact of Halogens, Strong acids, Alkalies or Oxidizers.
Container and packaging materials for safe handling data is not available.
 

8. Exposure controls/personal protection
Control parameters
Adopted value
(Mineral Oil)
ACGIH(2010) TWA: as low as possible(L)(as Poorly and mildly refined Mineral oil, excluding
metal working fluids)(URT irr)
(Diethylene glycol monobutyl ether)
ACGIH(2013) TWA: 10ppm (IFV) (Hematologic, liver & kidney eff)
(Toluene)
ACGIH(2020) TWA: 20ppm (CNS, visual, & hearing impair; female repro system eff; pregnancy
loss)
[ACGIH] Notation
(Toluene)
OTO
Exposure controls
Appropriate engineering controls
Exhaust/ventilator should be available.
Washing facilities should be available.
Individual protection measures
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Hand protection
Wear protective gloves.
Eye protection
Use safety goggles when necessary.
Skin and body protection
Wear impervious clothing and boots in case of repeated or prolonged treatment.
 

9. Physical and Chemical Properties
Information on basic physical and chemical properties
Physical state: Non water-soluble liquid
Color: Clear, Brown
Odor: Slight odor
Melting point/Freezing point data is not available.
Boiling point or initial boiling point data is not available.
Boiling range data is not available.
Flammability (gases, liquids and solids) data is not available.
Lower and upper explosion limit/flammability limit:
Lower explosion limit: (Estimated)1vol %
Upper explosion limit: (Estimated)7vol %
Flash point: (Cleveland open cup method)260℃
Auto-ignition temperature: No information
Decomposition temperature: No information
Self-Accelerating Decomposition Temperature/SADT: No information
Kinematic viscosity: 168mm2/s(40℃)
Solubility:
Solubility in water: Insoluble
n-Octanol/water partition coefficient: No information
Vapor pressure: No information
Vapor density: No information
Density and/or relative density: 0.888g/cm3(15℃)
Particle characteristics: No information
Evaporation rate data is not available.
VOC: No information
Radioactivity: No information
Bulk density: No information
 

10. Stability and Reactivity
Chemical stability
Stable under normal storage/handling conditions.
Conditions to avoid
No useful information at present.
Incompatible materials
Strong acids, Bases, Oxidizing agents,Halogens
Hazardous decomposition products
No useful information at present.
 

11. Toxicological Information
Information on toxicological effects
Acute toxicity
Acute toxicity (Inhalation)
[Data for components of the product]
[GHS Cat. Japan, base data]
(Toluene)
vapor: rat LC50=3319-8800ppm/4hr (EU-RAR, 2003) et al.
Labor standard Act, Japan; Chemical substances or compounds (including alloys) causing disease
Toluene
Irritant properties
Skin corrosion/irritation
[Data for components of the product]
[GHS Cat. Japan, base data]
(Toluene)
rabbit moderate irritation (EU-RAR, 2003)
Serious eye damage/irritation
[Data for components of the product]
[GHS Cat. Japan, base data]
(Diethylene glycol monobutyl ether)
rabbit recover within 14 days (PATTY 6th, 2012 et al)
(Toluene)
rabbit slight eyes irritation (EU-RAR, 2003)
Allergenic and sensitizing effects data is not available.
Mutagenic effects data is not available.
Carcinogenicity
[Data for components of the product]
[IARC]
(Mineral Oil)
Group 1 : Carcinogenic to humans
(Toluene)
Group 3 : Not classifiable as to its carcinogenicity to humans
[ACGIH]
(Mineral Oil)
A2(as Poorly and mildly refined Mineral oil, excluding metal working fluids)(2010) :
Suspected Human Carcinogen
(Toluene)
A4(2020) : Not Classifiable as a Human Carcinogen
[JSOH]
(Mineral Oil)
Group 1: The agents which are carcinogenic to humans (as mineral oil mist)
[EU]
(Mineral Oil)
Category 1B; Substances presumed to have carcinogenic potential for humans
Teratogenic effects data is not available.
Reproductive toxicity data is not available.
Specific target organ toxicity (STOT)
STOT-single exposure
[Data for components of the product]
[cat.3 (respiratory tract irritation)]
[GHS Cat. Japan, base data]
(Toluene)
respiratory tract irritation (PATTY 5th, 2001)
[cat.3 (narcotic effects)]
[GHS Cat. Japan, base data]
(Diethylene glycol monobutyl ether)
narcotic effect (DFGOT vol. 7, 1996)
(Toluene)
narcotic effect (EHC 52, 1985; IARC 47, 1989)
Aspiration hazard data is not available.
 

12. Ecological Information
Toxicity
Aquatic toxicity
[Data for components of the product]
Hazardous to the aquatic environment, short-term (acute)
[GHS Cat. Japan, base data]
(Diethylene glycol monobutyl ether)
Fish (bluegill) LC50=1300mg/L/96hr,Crustacea (Daphnia magna) EC50 > 100mg/L/48hr,Algae
(Desmodesmus subspicatus) EC50 > 100mg/L/96hr (EURAR, 1999)
(Toluene)
Crustacea (Ceriodaphnia dubia) EC50=3.78mg/L/48hr (NITE Initial Risk Assessment Report, 2006)
Hazardous to the aquatic environment, long-term (chronic)
[GHS Cat. Japan, base data]
(Toluene)
Crustacea (Ceriodaphnia dubia) NOEC=0.74mg/L/7days (NITE Initial Risk Assessment Report, 2006)
Water solubility
(Diethylene glycol monobutyl ether)
100 g/100 ml (PHYSPROP_DB, 2009)
(Toluene)
none (ICSC, 2002)
Persistence and degradability
[Data for components of the product]
(Toluene)
BOD_Degradation : 123% (METI existing chemical safety inspections)
Bioaccumulative potential
[Data for components of the product]
(Diethylene glycol monobutyl ether)
log Pow=0.3 (ICSC, 2004)
(Toluene)
log Kow=2.73 (PHYSPROP DB, 2008)
Mobility in soil
Mobility in soil data is not available.
Other adverse effects
Ozone depleting chemical data is not available.
 

13. Disposal considerations
Description of waste residues and information on their safe handling and methods of disposal,
including the disposal of any contaminated packaging
Waste treatment methods
Dispose of contents/container in accordance with local/national regulation.
Dispose to an authorized waste collection point.
Contaminated packing
This container can be recovered for reuse or recycling after cleaning.
Execute appropriate disposal according to the related regulations or to a local public body.
 

14. Transport Information
Environmental hazards
Marine pollutants (yes/no) : no
Special precautions for user
In conveyance, check there is no leak from container and that having specified
representation. Load container be careful with fall and damage, and conducting load
collapse prevention reliably.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Noxious Liquid Substances ; Cat. Y
Toluene; Poly(isobutylene)
Noxious Liquid Substances ; Cat. Z
sulfonic acids, petroleum, calcium salts; Diethylene glycol monobutyl ether
 

15. Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or mixture
U.S. Toxic Substances Control Act (TSCA) Inventory
Chemicals listed in TSCA Inventory
Toluene; Diethylene glycol monobutyl ether; Poly(isobutylene); sulfonic acids,
petroleum, calcium salts; Mineral Oil
California proposition 65
WARNING: This product can expose you to chemical(s), which is(are) known to the State of
California to cause cancer, and/or chemical(s), which is (are) known to the State of
California to cause birth defects or other reproductive harm.
For more information go to www.P65Warnings.ca.gov.
Reproductive Toxicity
Toluene (Developmental Toxicity)
 

16. Other information
References and sources for data
Globally Harmonized System of classification and labelling of chemicals, UN
Recommendations on the TRANSPORT OF DANGEROUS GOODS 22nd edit., 2021 UN
IMDG Code, 2022 Edition (Incorporating Amendment 41-22)
IATA Dangerous Goods Regulations (65th Edition) 2024
EU REGULATION (EC) No. 1272/2008 (CLP), amended by COMMISSION REGULATION (EU) 2019/521
2020 EMERGENCY RESPONSE GUIDEBOOK (US DOT)
2024 TLVs and BEIs. (ACGIH)
JIS Z 7252 : 2019
JIS Z 7253 : 2019
2023 Recommendation on TLVs (JSOH)
Supplier's data/information
Hazard Communication Standard - 2012 (29 CFR 1910.1200)
Chemicals safety data management system "GHS Assistant" Version 4.27
(https://www.asahi-ghs.com/)
General Disclaimer
SDS (Safety Data Sheet) is offered to business operator who deals with harmful chemical
product, to ensure safety handling.
Business operator who deals with these materials must understand necessity to take
appropriate measures for each product with their own responsibility refer to this SDS.
Therefore, this SDS is not a guarantee for safety.
The GHS classification data given here is based on current EU official data.